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Just to add info to my question, Spider-Man#14 ('Sub-City' Part 2) was published in 1991.
He had the Alien Costume but then, after getting rid of it, followed the advice of Black Cat and wore a cloth version (she made the first one) as a spare. i.e.: red/blue is dirty, etc.
He continued using the cloth version (as a spare/extra one, even after Venom appeared) until at least 1991.
Did he ever wear it again?
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